FC Zürich Frauen – Juventus
Referee: Ainara Acevedo Dudley (ESP, photo)
Assistant Referee 1: Matilde Esteves-Garcia (ESP)
Assistant Referee 2: Rita Cabanero Mompo (ESP)
Fourth Official: Zulema Gonzalez Gonzalez (ESP)
Referee Observer: Esther Azzopardi Farrugia (MLT)
Bayern München – FC Rosengard
Referee: Jelena Cvetković (SRB)
Assistant Referee 1: Danijela Stojanović (SRB)
Assistant Referee 2: Ivana Jovanović (SRB)
Fourth Official: Milica Milovanović (SRB)
Referee Observer: Eleni Kyriou (GRE)
Olympique Lyonnais – Arsenal WFC
Referee: Ivana Projkovska (MKD)
Assistant Referee 1: Elena Soklevska-Ilievski (MKD)
Assistant Referee 2: Vjolca Izeiri (MKD)
Fourth Official: Irena Velevačkoska-Ristevski (MKD)
Referee Observer: Marta Bonaria Atzori (ITA)
FC Barcelona – SL Benfica
Referee: Alina Peșu (ROU)
Assistant Referee 1: Petruța Iugulescu (ROU)
Assistant Referee 2: Daniela Constantinescu (ROU)
Fourth Official: Cristina Trandafir (ROU)
Referee Observer: Sofia Karagiorgi (CYP)
20 October 2022
KFF Vllaznia – Real Madrid
Referee: Catarina Campos (POR)
Assistant Referee 1: Vanessa Gomes (POR)
Assistant Referee 2: Ana Silva (POR)
Fourth Official: Sara Alves (POR)
Referee Observer: Emilia Wnuk (POL)
VfL Wolfsburg – SKN St. Pölten
Referee: Abigail Byrne (ENG)
Assistant Referee 1: Melissa Burgin (ENG)
Assistant Referee 2: Georgia Ball (ENG)
Fourth Official: Louise Saunders (ENG)
Referee Observer: Lilach Asulin (ISR)
Paris St. Germain – Chelsea FCW
Referee: Ewa Augustyn (POL)
Assistant Referee 1: Katarzyna Wojs (POL)
Assistant Referee 2: Aleksandra Ulanowska (POL)
Fourth Official: Monika Mularczyk (POL)
Referee Observer: Jelena Banjeglav (SRB)
AS Roma – Slavia Praha
Referee: Volha Blockaja (BLR)
Assistant Referee 1: Nastassia Dančanka (BLR)
Assistant Referee 2: Darja Fiedčanka (BLR)
Fourth Official: Maryja Bujko (BLR)
Referee Observer: Paloma Quintero Siles (ESP)
Referee: Ainara Acevedo Dudley (ESP, photo)
Assistant Referee 1: Matilde Esteves-Garcia (ESP)
Assistant Referee 2: Rita Cabanero Mompo (ESP)
Fourth Official: Zulema Gonzalez Gonzalez (ESP)
Referee Observer: Esther Azzopardi Farrugia (MLT)
Bayern München – FC Rosengard
Referee: Jelena Cvetković (SRB)
Assistant Referee 1: Danijela Stojanović (SRB)
Assistant Referee 2: Ivana Jovanović (SRB)
Fourth Official: Milica Milovanović (SRB)
Referee Observer: Eleni Kyriou (GRE)
Olympique Lyonnais – Arsenal WFC
Referee: Ivana Projkovska (MKD)
Assistant Referee 1: Elena Soklevska-Ilievski (MKD)
Assistant Referee 2: Vjolca Izeiri (MKD)
Fourth Official: Irena Velevačkoska-Ristevski (MKD)
Referee Observer: Marta Bonaria Atzori (ITA)
FC Barcelona – SL Benfica
Referee: Alina Peșu (ROU)
Assistant Referee 1: Petruța Iugulescu (ROU)
Assistant Referee 2: Daniela Constantinescu (ROU)
Fourth Official: Cristina Trandafir (ROU)
Referee Observer: Sofia Karagiorgi (CYP)
20 October 2022
KFF Vllaznia – Real Madrid
Referee: Catarina Campos (POR)
Assistant Referee 1: Vanessa Gomes (POR)
Assistant Referee 2: Ana Silva (POR)
Fourth Official: Sara Alves (POR)
Referee Observer: Emilia Wnuk (POL)
VfL Wolfsburg – SKN St. Pölten
Referee: Abigail Byrne (ENG)
Assistant Referee 1: Melissa Burgin (ENG)
Assistant Referee 2: Georgia Ball (ENG)
Fourth Official: Louise Saunders (ENG)
Referee Observer: Lilach Asulin (ISR)
Paris St. Germain – Chelsea FCW
Referee: Ewa Augustyn (POL)
Assistant Referee 1: Katarzyna Wojs (POL)
Assistant Referee 2: Aleksandra Ulanowska (POL)
Fourth Official: Monika Mularczyk (POL)
Referee Observer: Jelena Banjeglav (SRB)
AS Roma – Slavia Praha
Referee: Volha Blockaja (BLR)
Assistant Referee 1: Nastassia Dančanka (BLR)
Assistant Referee 2: Darja Fiedčanka (BLR)
Fourth Official: Maryja Bujko (BLR)
Referee Observer: Paloma Quintero Siles (ESP)